The best replacement for narcotic is opioid.

The best alternatives to narcotic are rated as following:
★★★★★  opioid
★★★★★  controlled substance
★★★  opiate
★★★  barbiturate
★★  non narcotic
★★  sedative
★  hallucinogen
★  stimulant
★  nsaid
★  analgesic
  class 2 narcotic
  narcotic
  non-narcotic
  drug
  nonnarcotic
  hypnotic
  opioids

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No companions for narcotic have been suggested so far.
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Google Trends

Scale is based on the average worldwide traffic of narcotic in all years. Click on graph for more.
narcotic
opioid
controlled substance