The best replacement for barbiturate is benzodiazepine.

The best alternatives to barbiturate are rated as following:
★★★★★  benzodiazepine
★★★★★  narcotic
★★★  barbiturate
★★  opiate
★★  benzo
★  opioid
  non barbiturate

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Google Trends

Scale is based on the average worldwide traffic of barbiturate in all years. Click on graph for more.
barbiturate
benzodiazepine
narcotic