The best replacement for villain is villain.

The best alternatives to villain are rated as following:
★★★★★  villain
★★★  hero
★★★  anti hero
★★  hero quiz
★★  superhero
★★  antagonist
★★  victim
★★  hero dcuo
★  hero dc universe online
★  stomper
★  bhagavathi
★  scoundrel
★  victim merchant of venice
  hero batman
  jackson super hero
  veritas
  super villain
  dagger nomad
  traxxas blast
  globe castro

Your alternative for villain is not listed? Suggest!
Speaking about villain, one probably shouldn't forget about black and white mask.

Other search terms related to villain and their ratings are:
★★★★★ black and white mask
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villain
villain
hero