The best replacement for povidone iodine is chlorhexidine.

The best alternatives to povidone iodine are rated as following:
★★★★★  chlorhexidine
★★★★  betadine
★★  iodine
★★  tincture of iodine
★  chlorhexidine gluconate
★  potassium iodine
  iodine tincture
  lugol's
  tincture iodine

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povidone iodine
chlorhexidine
betadine