The best replacement for starmie is vaporeon.

The best alternatives to starmie are rated as following:
★★★★★  vaporeon
★★★★  cloyster
★★★★  kingdra
★★★★  lapras
★★★  milotic
★★★  gyarados
★★★  slowbro
★★★  greninja
★★★  alakazam
★★  tentacruel
★★  samurott
★★  slowking
★★  espeon
★★  gengar
★★  kingler
★  golduck
★  excadrill
★  staryu
★  swampert
★  lantern
  feraligatr
  blastoise
  wailord
  gardevoir
  poliwrath

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Google Trends

Scale is based on the average worldwide traffic of starmie in all years. Click on graph for more.
starmie
vaporeon
cloyster