The best replacement for unsweetened cocoa is baking cocoa.

The best alternatives to unsweetened cocoa are rated as following:
★★★★★  baking cocoa
★★★★★  unsweetened chocolate
★★★  cacao
★★★  cocoa powder
★★  dutch process
★  cocoa
★  dutch process cocoa

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Google Trends

Scale is based on the average worldwide traffic of unsweetened cocoa in all years. Click on graph for more.
unsweetened cocoa
baking cocoa
unsweetened chocolate