The best replacement for toxicroak is lucario.

The best alternatives to toxicroak are rated as following:
★★★★★  lucario
★★★★  drapion
★★★  breloom
★★  scrafty
★★  heracross
★★  greninja
★★  croagunk
★★  pangoro
★★  gallade
★  nidoking
★  mienshao
  skuntank
  medicham
  seismitoad
  conkeldurr

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toxicroak
lucario
drapion