The best replacement for tempera is oil.

The best alternatives to tempera are rated as following:
★★★★★  oil
★★★★  fresco
★★★★  acrylic paint
★★★  poster paint
★★★  watercolor
★★★  gouache
★★  oil painting
★★  finger paint
★★  washable paint
★  oil paint
  egg tempera

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tempera
oil
fresco