The best replacement for styrene is polystyrene.

The best alternatives to styrene are rated as following:
★★★★★  polystyrene
★★★★  sintra
★★★★  abs
★★  plexiglass
★  melamine
★  foam core
★  gator board
  masonite
  mat board
  rigid vinyl
  wonderflex
  petg
  coroplast

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Google Trends

Scale is based on the average worldwide traffic of styrene in all years. Click on graph for more.
styrene
polystyrene
sintra