The best replacement for steam distillation is simple distillation.

The best alternatives to steam distillation are rated as following:
★★★★★  simple distillation
★★★  reverse osmosis
★★★  fractional distillation
★★  solvent extraction
★  co2 extraction
★  vacuum distillation
  hydrodistillation
  normal distillation

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steam distillation
simple distillation
reverse osmosis