The best replacement for sodium fluoride is sodium monofluorophosphate.

The best alternatives to sodium fluoride are rated as following:
★★★★★  sodium monofluorophosphate
★★★★★  calcium fluoride
★★★  fluoride
★★  stannous fluoride
★★  stannous
★  cetylpyridinium chloride
★  hydrofluorosilicic acid
★  fluoride ion
★  fluorosilicic acid
  potassium fluoride
  fluorine
  neutral sodium fluoride

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sodium fluoride
sodium monofluorophosphate
calcium fluoride