The best replacement for riolu is pancham.

The best alternatives to riolu are rated as following:
★★★★★  pancham
★★★★★  chimchar
★★★  mienfoo
★★★  shinx
★★  scraggy
★★  zorua
★★  snivy
★★  emboar
★  tyrogue
★  timburr
★  mareep

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riolu
pancham
chimchar