The best replacement for pyrodex is black powder.

The best alternatives to pyrodex are rated as following:
★★★★★  black powder
★★★★★  triple 7
★★★★★  777
★★★★★  triple seven
★★★  goex
★★  blackhorn 209
★  triple seven pellets
★  777 pellets
★  white hots
★  triple 777
★  triple 7 powder
★  triple se7en
  american pioneer
  powder
  triple seven powder
  blackhorn

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pyrodex
black powder
triple 7