The best replacement for potato starch is flour.

The best alternatives to potato starch are rated as following:
★★★★★  flour
★★★★★  potato flour
★★★★  cornstarch
★★★★  corn starch
★★★★  tapioca starch
★★★  arrowroot
★★  rice starch
★★  arrowroot powder
★  potato flakes
★  tapioca flour
★  potato starch flour
★  rice flour
★  sweet potato starch
★  corn flour
  potato starch
  arrowroot starch
  wheat starch

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potato starch
flour
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