The best replacement for polynicotinate is picolinate.

The best alternatives to polynicotinate are rated as following:
★★★★★  picolinate
★★★★  chromium picolinate
★★  gtf chromium
★★  chromium nicotinate
★  chromium
  gtf

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No companions for polynicotinate have been suggested so far.
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polynicotinate
picolinate
chromium picolinate