The best replacement for octahedral is tetrahedral.


The best alternatives to octahedral are rated as following:
★★★★★  tetrahedral
★★★★  square planar
★★  square bipyramidal
★  tetrahedral splitting
★  trigonal prismatic

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No companions for octahedral have been suggested so far.
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Google Trends

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octahedral
tetrahedral
square planar