The best replacement for grain alcohol is vodka.

The best alternatives to grain alcohol are rated as following:
★★★★★  vodka
★★★  moonshine
★★  isopropyl alcohol
★★  everclear
★★  rubbing alcohol
★★  wood alcohol
★★  ethyl alcohol
  denatured alcohol

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Google Trends

Scale is based on the average worldwide traffic of grain alcohol in all years. Click on graph for more.
grain alcohol
vodka
moonshine