The best replacement for cotton socks is wool socks.

The best alternatives to cotton socks are rated as following:
★★★★★  wool socks
★★★★★  polyester
★★★  synthetic socks
★★  acrylic socks
★  no socks
  merino wool socks
  wool
  nylon socks

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Google Trends

Scale is based on the average worldwide traffic of cotton socks in all years. Click on graph for more.
cotton socks
wool socks
polyester