The best replacement for carbohydrate is starch.

The best alternatives to carbohydrate are rated as following:
★★★★★  starch
★★★★  protein
★★★  lipid
★★★  hydrocarbon
★★  calorie
★  simple carbohydrate
★  fat metabolism
★  polysaccharide
★  high protein
★  protein energy
  complex carbohydrate

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No companions for carbohydrate have been suggested so far.
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Google Trends

Scale is based on the average worldwide traffic of carbohydrate in all years. Click on graph for more.
carbohydrate
starch
protein