The best replacement for black iron is elite knight.

The best alternatives to black iron are rated as following:
★★★★★  elite knight
★★★★  carbon steel
★★★★  giant set
★★★  havel
★★★  galvanized steel
★★★  giant armor
★★  paladin dark souls
★★  galvanized
★★  galvanized iron
★  csst
★  galvanized pipe
★  stone armor
★  black steel
  steel dark souls
  giants

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black iron
elite knight
carbon steel