The best replacement for amylopectin is amylose.

The best alternatives to amylopectin are rated as following:
★★★★★  amylose
★★★  guar gum
★★★  amylose structure
★★  pectin
★★  glycogen

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No companions for amylopectin have been suggested so far.
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Google Trends

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amylopectin
amylose
guar gum