The best replacement for unsaturated hydrocarbon is saturated hydrocarbon.

The best alternatives to unsaturated hydrocarbon are rated as following:
★★★★★  saturated hydrocarbon
★★★  unsaturated

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No companions for unsaturated hydrocarbon have been suggested so far.
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Google Trends

Scale is based on the average worldwide traffic of unsaturated hydrocarbon in all years. Click on graph for more.
unsaturated hydrocarbon
saturated hydrocarbon
unsaturated