The best replacement for piplup is chimchar.

The best alternatives to piplup are rated as following:
★★★★★  chimchar
★★★★  turtwig
★★  oshawott
★★  prinplup
★★  totodile
★  glaceon
★  empoleon
★  pansage
  ash crimson
  oshwatt
  mudkip
  torchic
  squirtle
  oshwatta

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No companions for piplup have been suggested so far.
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Google Trends

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piplup
chimchar
turtwig