The best replacement for ionization is dissociation.

The best alternatives to ionization are rated as following:
★★★★★  dissociation
★★★★  photoelectric
★★★  photoelectric smoke detectors
★  hydrolysis
★  photoelectric smoke alarms
★  electronegativity
★  photoelectric smoke detector
★  excitation
★  electron ionization
★  optical smoke detectors
★  photoelectric detectors
★  photoelectric smoke alarm
  electron affinity
  ionisation
  ozonation
  photoelectric fire alarms
  optical smoke detector
  photo smoke detectors
  photoelectric smoke detector better
  oxidation
  salt water pools
  photocell smoke detectors

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ionization
dissociation
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