The best replacement for coffee caffeine is tea caffeine.

The best alternatives to coffee caffeine are rated as following:
★★★★★  tea caffeine
★★★  coke
★★  green tea
★★  decaf
★★  tea
★★  espresso
★  energy drinks
★  espresso caffeine
★  red bull
  green tea caffeine

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Google Trends

Scale is based on the average worldwide traffic of coffee caffeine in all years. Click on graph for more.
coffee caffeine
tea caffeine
coke