The best replacement for chili pepper is chili powder.

The best alternatives to chili pepper are rated as following:
★★★★★  chili powder
★★★  cayenne pepper
★★★  chile pepper
★★★  jalapeno pepper
★★  jalapeno
★★  red pepper
★★  habanero
★  cayenne
★  chipotle chili powder
  jalapeno hotter
  ancho chili powder

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chili pepper
chili powder
cayenne pepper