The best replacement for capilene is polypropylene.

The best alternatives to capilene are rated as following:
★★★★★  polypropylene
★★★★  merino
★★★  under armour
★★★  polartec
★★  merino wool
★  smartwool
★  merino patagonia
  duofold
  icebreaker

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Google Trends

Scale is based on the average worldwide traffic of capilene in all years. Click on graph for more.
capilene
polypropylene
merino